cover.daftar isi, dewan redaksi dan sertifikat_Insertion of bentonite with Organometallic[Fe3O(OOC6H5)6(H2O)3(NO3).nH2O] as Adsorbent of Congo Red

Said, Muhammad (2017) cover.daftar isi, dewan redaksi dan sertifikat_Insertion of bentonite with Organometallic[Fe3O(OOC6H5)6(H2O)3(NO3).nH2O] as Adsorbent of Congo Red. In: International Conference on Chemistry and Material Science (IC2MS) 2017, 4-5 november 2017, malang.

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Abstract

: The adsorption of Congo red using bentonite inserted organometallic has been investigated. The insertion bentonite was characterized using FT-IR Spectrophotometer, XRD and XRF analysis. The FT-IR characterization showed the higher intensity of peak wavenumber at 470.6 cm-1 for Fe3O on the ratio 1:3. While the XRD characterization showed the shift of diffraction angle of 2θ was 5.2° and has a basal spacing of 16.8 Ǻ. In the XRF characterization, the insertion process of organometallic occurred optimally with the percentage of metal oxide reached 71.75 %. The adsorption process of bentonite inserted organometallic compound [Fe3O(OOC6H5)6(H2O)3(NO3)·nH2O] showed the adsorption rate (k) is 0.050 min-1 , the largest adsorption capacity (b) at 70o C is 4.48 mol/g, the largest adsorption energy at temperature 30o C which is 6.4 kJ/mol Organometallic compounds. The value of the enthalpy (ΔH) and entropy (ΔS) decreased with increasing concentrations of the Congo red. Effect of pH on the adsorption on at pH 3 shows the biggest of number Congo red absorbed is 19.52 mg/L for insertion of bentonite.

Item Type: Conference or Workshop Item (Paper)
Subjects: #3 Repository of Lecturer Academic Credit Systems (TPAK) > Conference or Workshop
#3 Repository of Lecturer Academic Credit Systems (TPAK) > Articles Access for TPAK (Not Open Sources)
Divisions: 08-Faculty of Mathematics and Natural Science > 47201-Chemistry (S1)
Depositing User: Dr Muhammad Said
Date Deposited: 11 May 2023 00:09
Last Modified: 11 May 2023 00:09
URI: http://repository.unsri.ac.id/id/eprint/100377

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