Noble-free oxygen reduction reaction catalyst supported on Sengon wood (Paraserianthes falcataria L.) derived reduced graphene oxide for fuel cell application. Artikel

Wulandhari Sudarsono, - and Wai Yin Wong, - and Kee Shyuan Loh, - and Edy Herianto Majlan, - and Nirwan Syarif, - and Kuan-Ying Kok, - and Rozan Mohamad Yunus, - and Kean Long Lim, - (2019) Noble-free oxygen reduction reaction catalyst supported on Sengon wood (Paraserianthes falcataria L.) derived reduced graphene oxide for fuel cell application. Artikel. International Journal of Energy Research. pp. 1-14. ISSN 1099-114X

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Abstract

Reduced graphene oxide (RGO) has progressed as one of key emerging carbon for catalyst support material. As an alternative to the conventional RGO precursor, bio-mass Sengon wood was converted into RGO for use as a noble metal free catalyst support in oxygen reduction reaction (ORR). This work intends to reveal the applicability of Sengon wood-derived RGO in anchoring/doping iron and nitrogen particles onto its surface and to study its ORR performance in a half-cell environment. Thin sheet layer and highly defective (ID /IG) was gradually obtained at elevated pyrolysis temperature of Sengon wood graphene oxide (GO) at range 700 ? C to 900 ? C. As prepared RGO was further doped into catalyst (Fe/N/RGO) through the same pyrolysis procedure at a selected temperature after mixing the GO powder with iron chloride and different nitrogen precursors (urea, choline chloride, and polyaniline) at a fixed ratio. The ORR activity reached a current density up to 2.43 mA/cm 2 , which in conjunction with smooth multilayer sheet morphology and high graphitic-N content as the active sites. Stability analysis indicated an 85% current efficiency and only 0.03-V reduction in onset potential on methanol resistant test for Fe/ChoCl/RGO catalyst. This study revealed that Sengon wood-derived RGO successfully supported Fe-N-C catalyst which showed comparable oxygen reduction activity to Pt/C.

Item Type:	Article
Subjects:	#3 Repository of Lecturer Academic Credit Systems (TPAK) > Articles Access for TPAK (Not Open Sources)
Divisions:	08-Faculty of Mathematics and Natural Science > 47201-Chemistry (S1)
Depositing User:	Dr Nirwan Syarif
Date Deposited:	20 Jun 2023 02:15
Last Modified:	20 Jun 2023 02:15
URI:	http://repository.unsri.ac.id/id/eprint/108844

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