Said, Muhammad and Dian, Afifah Rahma and Mohadi, Risfidian and Lesbani, Aldes (2022) Cr/Al Pillared Bentonite and Its Application on Congo Red and Direct Blue Removal (Similarity). Turnitin Universitas Sriwijaya. (Submitted)
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Abstract
Bentonite was modified through pillarization with metal oxide Cr/Al in 2:1 and 1:2 ratio to obtain larger basal spacing of bentonite-layered structure. Pillarization was conducted via intercalation method at room temperature followed by calcination. The result was characterized by using XRD and FT-IR Spectrophotometer. XRD pattern shown pillarization by Cr/Al 2:1 ratio gave peak at 2θ 5.3° which is correspond to d = 16.4 Å. At 1:2 Cr/Al ratio, peak appears at 2θ 6.4° that is related to d = 13.7 Å. FTIR Spectroscopy measurement gave inconclusive result. The Cr/Al pillared bentonite at 2:1 ratio was applied as adsorbent on Congo red and Direct blue dyes. The result indicates the adsorption follows Freundlich isotherm. Adsorption rate for both dyes follows pseudo-second order with rate constant of pillared bentonite higher than natural one. Adsorption isotherm concludes that Freundlich isotherm is favorable compare to Langmuir. Thermodynamic evaluation suggests that isotherm occurs spontaneously in an exothermic process.
| Item Type: | Other |
|---|---|
| Subjects: | #3 Repository of Lecturer Academic Credit Systems (TPAK) > Results of Ithenticate Plagiarism and Similarity Checker |
| Divisions: | 08-Faculty of Mathematics and Natural Science > 47102-Chemistry (S2) |
| Depositing User: | Dr.rer.nat Risfidian Mohadi |
| Date Deposited: | 27 Aug 2022 13:25 |
| Last Modified: | 27 Aug 2022 13:25 |
| URI: | http://repository.unsri.ac.id/id/eprint/77852 |
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