HANIFAH, YULIZAH and Mohadi, Risfidian and Mardiyanto, Mardiyanto and Lesbani, Aldes (2023) Polyoxometalate Intercalated MgAl-Layered Double Hydroxide for Degradation of Malachite Green. Ecological Engineering & Environmental Technology, 24 (2). pp. 109-119. ISSN 2719-7050
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Abstract
ABSTRACT Improving the selectivity of photocatalysis of LDH pristine (MgAl-LDH) and LDH composite (MgAl-SiW12O40] and MgAl-[PW12O40]) was synthesized and used for degraded malachite green (MG). The effects of the amount of catalyst, pH value, and reaction times on degradation performance were discussed. MG degraded better composites than LDH pristine. The results indicated that MgAl-LDH was successfully synthesized by showing the peak diffractions at angles 10.39°(003), 20.17°(006), and 34.8°(009). Both kinds of attained MgAl-[SiW12O40] and MgAl-[PW12O40] had the typical structure of LDH that proved by appeared diffraction at 2θ angles 7.73°, 28.6°, 35.6° for MgAl-[PW12O40] and at 2θ angles 8.61°, 24.27°, 34.96° and 66.34° for MgAl-[SiW12O40]. The FTIR result indicates materials used for fifth regeneration, which confirmed the LDH composite structure. The fotodegradation activity of MG for pristine MgAl LDH (56.1%), composites MgAl-Pw (84.6%) and MgAl-Si (87.8%), respectively. The successful ability of photodegradation process by the percentage of degradation on material LDH-polyoxometalate composite showed the increasing of photodegradation catalytic and the regeneration ability of LDH pristine.
| Item Type: | Article |
|---|---|
| Subjects: | Q Science > QD Chemistry > QD146-197 Inorganic chemistry |
| Divisions: | 08-Faculty of Mathematics and Natural Science > 47102-Chemistry (S2) |
| Depositing User: | Dr.rer.nat Risfidian Mohadi |
| Date Deposited: | 25 Dec 2022 10:52 |
| Last Modified: | 25 Dec 2022 10:52 |
| URI: | http://repository.unsri.ac.id/id/eprint/84588 |
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