Synthesis, Characterization of ZSM-5 Catalyst for Catalytic Pyrolysis of Empty Fruit Bunches

Rahmiyati, Lutfia and Arita, Susila and Komariah, Leily Nurul and Nazaruddin, Nazaruddin and Alfernando, Oki (2019) Synthesis, Characterization of ZSM-5 Catalyst for Catalytic Pyrolysis of Empty Fruit Bunches. Indonesian Journal of Fundamental and Applied Chemistry. ISSN e-ISSN: 2540 9409 p-ISSN: 2540 9395

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Abstract

ZSM-5 is known as a heterogeneous catalyst in the process of petroleum cracking. Zeolite has narrow pores so it needs synthesis to form mesopore so that reactant molecules can enter the active site in ZSM-5 mesopore. In this study, mesopore formation was carried out by adding Si/Al components with a ratio of 20 derived from tetraethyl orthosilicate, aluminum isopropoxide and TPAOH template with hydrothermal process. The resulting ZSM-5 was characterized using x-ray diffraction, scanning and electron microscopy (SEM). The XRD characterization results showed that the ZSM-5 synthesized to form mesopore was seen from a fairly high peak intensity in the range at 2-theta were 8.11, 9.01°; 23.27°; 23.49°; and 24.13°. The results of this study already have the same structure as the commercial ZSM-5. Characterization of SEM-EDS showed that Si-Al and Na elements in ZSM5 were 96.43%, 3.56% and 0% wt, respectively. With a magnification of 20000x, this cluster is quite homogeneous even though the crystallization formed is not well aggregated. This ZSM-5 catalyst will be applied to the process of biomass into bio-oil.

Item Type: Article
Uncontrolled Keywords: ZSM-5 catalyst, zeolite, hydrotermal treatment, tetraethyl orthosilicate
Subjects: T Technology > TP Chemical technology > TP1-1185 Chemical technology > TP159.C3.A348 Catalysts. TECHNOLOGY & ENGINEERING / Material Science
Divisions: Faculty of Engineering > 24101-Chemical Engineering (S2)
Depositing User: Dr. Susila Arita Rachman
Date Deposited: 22 Jun 2020 14:12
Last Modified: 22 Jun 2020 14:12
URI: http://repository.unsri.ac.id/id/eprint/30600

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