Catalytic dehydration of 2‑propanol over nickel phosphide immobilized on natural bentonite (Penulis Korespondensi)

Hasanudin, Hasanudin and ASRI, WAN RYAN and HUSNIA, LEPA and Fanani, Zainal and Maryana, Roni and Al Muttaqii, Muhammad and Zhu, Zongyuan and Sagadevan, Suresh (2023) Catalytic dehydration of 2‑propanol over nickel phosphide immobilized on natural bentonite (Penulis Korespondensi). Springer Nature. (Unpublished)

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Abstract

This study investigated the fabrication of nickel phosphide immobilized on natu- ral bentonite (NiP/bentonite) as a low-cost catalyst with different metal loadings (mEq/g) to produce diisopropyl ether (DIPE) as a potential gasoline additive. The catalysts were prepared using a simple wet-impregnation method. The physico- chemical features of the parent natural bentonite and NiP/bentonite were analyzed using FTIR, SEM–EDX, XRD, N2 physisorption, and catalyst acidity using the NH3 gravimetric method. The dehydration reaction was conducted under mild conditions (150 °C for 3 h) using a reflux system. The results suggested that the NiP species did not alter the bentonite structure while increasing its acidity and surface area prop- erties. Using the 8 mEq/g NiP/bentonite catalyst, a DIPE product of 68.52% was achieved owing to the highly acidic sites of the catalyst and high stability over three cycles. This study highlights the potential of nickel-phosphide-supported natural bentonite in the dehydration reaction for DIPE production

Item Type:	Other
Subjects:	#3 Repository of Lecturer Academic Credit Systems (TPAK) > Corresponding Author
Divisions:	08-Faculty of Mathematics and Natural Science > 47201-Chemistry (S1)
Depositing User:	Dr. Hasanudin Hasanudin
Date Deposited:	06 Apr 2023 13:15
Last Modified:	06 Apr 2023 13:15
URI:	http://repository.unsri.ac.id/id/eprint/94143

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